On Wednesday, Athletic Bilbao eliminated Barcelona from the Copa del Rey with a 4-2 victory at home.
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Williams brothers, Inaki and Nico, scored in extra time during an incredible quarterfinal.
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Within the first minute, Gorka Guruzeta's rebound goal gave the hosts an early lead.
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But Barca scored two goals in five minutes to respond before the half.
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Yuri Berchiche of Athletic attempted to clear the ball from his own six-yard box in the 27th minute, but it cannoned off Robert Lewandowski and into the empty net.
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Subsequently, Lamine Yamal displayed a moment of brilliance as he bounded past three defenders to reach the edge of the box, where he cut inside and skillfully placed a strike just inside.
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But Athletic rallied after the interval, tying the score in the 49th minute by a powerful header from Oihan Sancet after Nico Williams' excellent cross from the left.
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Athletic converted their superiority into goals in the extra period. Nico Williams scored the second goal, followed by Inaki Williams.
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